102393-49-7

Basic information

• Product Name: cyclohexyl cis-2-vinylcyclopropyl ketone
• CAS NO: 102393-49-7
• Molecular Weight: 178.274
• Mol File: 102393-49-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cyclohexyl cis-2-vinylcyclopropyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl cis-2-vinylcyclopropyl ketone(102393-49-7)
• EPA Substance Registry System: cyclohexyl cis-2-vinylcyclopropyl ketone(102393-49-7)

Safety Data

• Hazardous Substances Data: 102393-49-7(Hazardous Substances Data)

Upstream product

• 15136-01-3 trans-1-bromo-2-vinylcyclopropane 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 5398-65-2 1,1-dibromo-2-vinylcyclopropane 
• 15136-01-3 cis-1-bromo-2-vinylcyclopropane 

Downstream Products

• 71647-81-9 (1-Cyclohexyl-2-methylene-cyclopent-3-enyloxy)-trimethyl-silane 
• 71647-82-0 1-Cyclohexyl-2-methylene-cyclopent-3-enol 
• 102393-60-2 tert-Butyl-(1-cyclohexyl-2-methylene-cyclopent-3-enyloxy)-dimethyl-silane 
• 102393-79-3 tert-Butyl-[cyclohexylidene-((1R,2S)-2-vinyl-cyclopropyl)-methoxy]-dimethyl-silane 
• 102393-57-7 tert-Butyl-{cyclohexyl-[2-vinyl-cycloprop-(Z)-ylidene]-methoxy}-dimethyl-silane 
• 102393-79-3 tert-Butyl-[cyclohexylidene-((1R,2R)-2-vinyl-cyclopropyl)-methoxy]-dimethyl-silane 

Relevant articles and documents

THERMAL REARRANGEMENT OF FUNCTIONALIZED 1,2-DIVINYLCYCLOPROPANE SYSTEMS. A CONVENIENT SYNTHESIS OF SUBSTITUTED 4-CYCLOHEPTEN-1-ONES

Reaction of the acyl chlorides 14-21 with lithium (phenylthio)(cis-2-vinylcyclopropyl)cuprate (2) provided the ketones 22-29.Compounds 22-25, upon treatment with i-Pr2NLi-Me3SiCl, were converted cleanly into the enol silyl ethers 30-33, which gave the 1,4