102396-70-3

Basic information

• Product Name: (1S,2R)-2-Dodecyl-1-methyl-cyclobutanol
• CAS NO: 102396-70-3
• Molecular Weight: 254.456
• Mol File: 102396-70-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S,2R)-2-Dodecyl-1-methyl-cyclobutanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R)-2-Dodecyl-1-methyl-cyclobutanol(102396-70-3)
• EPA Substance Registry System: (1S,2R)-2-Dodecyl-1-methyl-cyclobutanol(102396-70-3)

Safety Data

• Hazardous Substances Data: 102396-70-3(Hazardous Substances Data)

Upstream product

• 2922-51-2 heptadecan-2-one 

Relevant articles and documents

LIQUID-CRYSTALLINE SOLVENTS AS MECHANISTIC PROBES. 23. NORRISH II REACTIONS OF 2- AND SYM-ALKANONES IN THE ISOTROPIC, SMECTIC B, AND CRYSTALLINE PHASES OF n-BUTYL STEARATE.

n-Alkanones with the carbonyl group at the 2 or central positions (1 and 2, respectively) have been irradiated in the isotropic, smectic B, and two solid phases of n-butyl stearate (BS).The lengths of the ketones were varied from 11 to 31 carbons.The ratios of elimination/cyclization products and diastereomeric cyclobutanol products were measured for each as a function of temperature and BS phase.The effect of 1 and 2 on the phase transition temperatures of BS has been correlated with changes in the product ratios.The experiments demonstrate that a very sensitive cooperative relationship exists between the ease with which 1 and 2 fit into the ordered phases of BS and the degree to which the solvent matrices influence ketone photochemistry.The influence of solvent order on the product ratios is distinctly different for 1 and 2, and for the two product ratios from one ketone.