10242-38-3Relevant articles and documents
Synthesis and characterization of a new dioxime: Thermal and magnetic behavior of its heterotrinuclear BF+2-capped complexes
Uysal, Saban
, p. 2370 - 2378 (2010)
New heterotrinuclear complexes have been obtained from dinuclear Fe(III) oxygen-bridged N,N'-bis(salicylidene)ethylenediamine (salenH2) and bis(salicylidene)-o-phenylenediamine (salophH2) and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing [image omitted] caps have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by COO- groups. The structure of dioxime and its complexes were identified by using elemental analysis, magnetic susceptibility, thermal analysis, ICP-AES, 1H-NMR, and IR spectral data.
Electrical conductivity of chloro(phenyl)glyoxime and its Co(II), Ni(II) and Cu(II) complexes
Turkoglu, Orhan,Soylak, Mustafa,Belenli, Ibrahim
, p. 1233 - 1242 (2003)
Chloro(phenyl)glyoxime, a vicinal dioxime, and its Ni(II), Cu(II) and Co(II) complexes were prepared. XRD patterns of the complexes point to similar crystal structures. IR and elemental analysis data revealed the 1:2 metal-ligand ratio in the complexes. The Co(II) complex is a dihydrate. Temperature dependence of electrical conductivity of the solid ligand and its complexes was measured in the temperature range 25-250°C; it ranged between 10-14-10-6 Ω-1 cm-1 and increased with rising temperature. The activation energies were between 0.61-0.80 eV. The Co(II) complex has lower electric conductivity than the Ni(II) and Cu(II) complexes. This difference in the conductivity has been attributed to differences in the stability of the complexes.