1024617-08-0

Basic information

• Product Name: [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)]
• CAS NO: 1024617-08-0
• Molecular Weight: 555.827
• Mol File: 1024617-08-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)](CAS DataBase Reference)
• NIST Chemistry Reference: [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)](1024617-08-0)
• EPA Substance Registry System: [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)](1024617-08-0)

Safety Data

• Hazardous Substances Data: 1024617-08-0(Hazardous Substances Data)

Upstream product

• 7719-09-7 thionyl chloride 
• 1197040-29-1 phenyl isocyanate 
• 32857-07-1 2,4-di-tert-butyl-6-(1,1-dimethylaminomethyl)phenol 

Relevant articles and documents

Synthesis and ROMP activity of aminophenol-substituted tungsten(VI) and molybdenum(VI) complexes

Tungsten(VI) and molybdenum(VI) complexes [MO(L1)Cl2] and [M(X)(L2)Cl3] (X = O, NPh) with tridentate aminobis(phenolate) ligand L1 = methylamino-N,N-bis(2-methylene-4,6-dimethylphenolate) and bidentate aminophenolate ligand L2 = 2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate) were prepared and characterised. These complexes are principally stable in open atmosphere under ambient conditions. When activated with Et2AlCl, they exhibited high activity in ring-opening metathesis polymerisation (ROMP) of 2-norbornene (NBE) and its derivatives. Especially complexes [M(NPh)(L2)Cl3], which are easily available from corresponding metal oxides MO3 by a simple three-step synthesis, were found very efficient ROMP catalysts for NBE (M = Mo, W) and 2-norbornen-5-yl acetate (M = Mo).