102493-37-8

Basic information

• Product Name: N-<2-(diphenylphosphino)benzyl>-N-isopropylhydroxylamine
• Synonyms: N-<2-(diphenylphosphino)benzyl>-N-isopropylhydroxylamine
• CAS NO: 102493-37-8
• Molecular Weight: 349.412
• Mol File: 102493-37-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-<2-(diphenylphosphino)benzyl>-N-isopropylhydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-<2-(diphenylphosphino)benzyl>-N-isopropylhydroxylamine(102493-37-8)
• EPA Substance Registry System: N-<2-(diphenylphosphino)benzyl>-N-isopropylhydroxylamine(102493-37-8)

Safety Data

• Hazardous Substances Data: 102493-37-8(Hazardous Substances Data)

Upstream product

• 50777-76-9 (2-formylphenyl)(diphenyl)phosphine 
• 5080-22-8 N-isopropylhydroxyamine 

Downstream Products

• 176099-10-8 N-[2-(diphenylphosphino)benzyl]-N-isopropyl-O-acetylhydroxylamine 
• 102493-38-9 N-<2-(diphenylphosphinyl)benzyl>-N-isopropylamine 

Relevant articles and documents

The endocyclic restriction test: Determination of the transition-structure geometry for the transfer of oxygen from N,N-dialkylhydroxylamines to triarylphosphines

The transfers of oxygen from nitrogen to phosphorus in the conversions of 1 to 2 and 3 to 4 are shown by kinetic, solvent-labeling, and double-labeling criteria to be intramolecular reactions. This information in conjunction with the stabilities of 13 and 14 is taken to rule out the mechanisms of classic linear SN2 substitutions at oxygen or nitrogen, biphilic insertion, or a radical chain reaction and to favor reactions via a 10-P-5 species (18). These results appear to provide the first experimental demonstration that oxygen can be transferred at an oblique angle.