102493-46-9

Basic information

• Product Name: IrH₂(H₂)2(P(C₆H₁₁)3)2⁽¹⁺⁾
• CAS NO: 102493-46-9
• Molecular Weight: 759.135
• Mol File: 102493-46-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: IrH₂(H₂)2(P(C₆H₁₁)3)2⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: IrH₂(H₂)2(P(C₆H₁₁)3)2⁽¹⁺⁾(102493-46-9)
• EPA Substance Registry System: IrH₂(H₂)2(P(C₆H₁₁)3)2⁽¹⁺⁾(102493-46-9)

Safety Data

• Hazardous Substances Data: 102493-46-9(Hazardous Substances Data)

Upstream product

• 65231-12-1 pentahydridobis(tricyclohexylphosphine)iridium(III) 
• 139733-42-9 pentahydridobis(tricyclohexylphosphine)iridium(III) 
• 40906-82-9 bis(trifluoromethylsulfonyl)phenylmethane 

Downstream Products

• 65231-12-1 pentahydridobis(tricyclohexylphosphine)iridium(III) 
• 101759-03-9 [IrH₂(CH₃CN)2(P(C₆H₁₁)3)2]⁽¹⁺⁾ 

Relevant articles and documents

Some Molecular Hydrogen Complexes of Iridium

The new molecular hydrogen complexes + (bq = 7,8-benzoquinolinate, L = PPh3 or PCy3) and + are described.A 1H NMR T1 criterion is proposed for detecting such complexes.Deprotonation of the coordinated H2 is described.The mechanism of hydrogenolysis of d0 alkyls is discussed and a dihydrogen complex proposed as intermediate.