102536-89-0Relevant articles and documents
Formation of quaternary carbon centers by highly regioselective hydroformylation with catalytic amounts of a reversibly bound directing group
Ueki, Yusuke,Ito, Hideto,Usui, Ippei,Breit, Bernhard
, p. 8555 - 8558 (2011)
Directly opposing Keulemans rule! Phosphinites work as reversibly bound directing groups allowing for the first highly regioselective hydroformylation of 3-substituted homoallylic alcohols to construct quaternary carbon centers. This method enables the at