1025719-26-9

Basic information

• Product Name: 1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene
• Synonyms: 1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene
• CAS NO: 1025719-26-9
• Molecular Weight: 288.238
• Mol File: 1025719-26-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene(1025719-26-9)
• EPA Substance Registry System: 1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene(1025719-26-9)

Safety Data

• Hazardous Substances Data: 1025719-26-9(Hazardous Substances Data)

Usage

General Description

1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene is a chemical compound used in organic chemistry as a reagent for various synthetic reactions. It is a benzene derivative with two isopropyl groups and a boron-containing substituent. The boron-containing group makes it useful as a boron source in organic synthesis, particularly in the formation of carbon-carbon bonds. It is also used as a ligand in coordination chemistry, where the boron center can coordinate with metal ions to form stable complexes. Overall, 1,3-diisopropyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborlan-2-yl)benzene plays a crucial role as a versatile building block in chemical synthesis and catalysis.

Upstream product

• 80058-84-0 4-bromo-2,6-diisopropylaniline 
• 24544-04-5 2,6-diisopropylbenzenamine 
• 23058-81-3 1-bromo-3,5-bis(propan-2-yl)benzene 
• 73183-34-3 bis(pinacol)diborane 
• 99-62-7 1,3-diisopropylbenzene 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Downstream Products

• 263397-82-6 (3,5-diisopropylphenyl)boronic acid 
• 1374116-12-7 1,3-diisopropyl-5-nitrosobenzene 

Relevant articles and documents

High-throughput optimization of Ir-catalyzed C-H borylation: A tutorial for practical applications

With the aid of high-throughput screening, the efficiency of Ir-catalyzed C-H borylations has been assessed as functions of precatalyst, boron reagent, ligand, order of addition, temperature, solvent, and substrate. This study not only validated some acce

ARGININE METHYLTRANSFERASE INHIBITORS AND USES THEREOF

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Synthesis, properties, and structure of tethered molybdenum alkylidenes

A new class of molybdenum alkylidenes has been prepared where the alkylidene is tethered to an imido ancillary ligand. The amine required for the synthesis is accessible in 38% yield in five steps from 1,3-diisopropylbenzene. The amine is then installed to generate the tethered alkylidene bis(triflate) complex, which was structurally characterized as its DME adduct. The Inflates are replaced by hexafluoro-terfbutoxide groups using the thallium salt of the alkoxide, and the bis(alkoxide) was characterized as its quinuclidine adduct. For comparison, an alkylidene bis(alkoxide) was prepared without the tether and having a formula similar to that of the tethered system. The structures from X-ray diffraction and NMR spectroscopy of the two complexes with and without the tether but with similar formulas are compared. The tether has the apparent effect, judging from JCH couplings in the alkylidene and angles in the solidstate structure, of reducing the strength of the a-agostic interaction. Four complexes were structurally characterized during this study: Mo[=N-2,4-Pr2iC6H2-2-CH 2CH2CMe2CH=](DME)(OTf)2, Mo(OBf)2, Mo(OBuF6t)2(quin)-[=N-2,4- Pr2iC6H2-2-CH2CH 2CMe2CH=], Mo[N(2,4-Pr2i-6-MeC 6H2)]2(neopentyl)2, and Mo(OBu F6t)2(quin)-[N(2,4-Pr2 i-6-MeC6H2)] [=C(H)But].