102599-25-7

Basic information

• Product Name: (+/-)-2r.3t-dibenzoyl-bicyclo[2.2.2]octene-⁽⁵⁾
• CAS NO: 102599-25-7
• Molecular Weight: 316.4
• Mol File: 102599-25-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-2r.3t-dibenzoyl-bicyclo[2.2.2]octene-⁽⁵⁾(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-2r.3t-dibenzoyl-bicyclo[2.2.2]octene-⁽⁵⁾(102599-25-7)
• EPA Substance Registry System: (+/-)-2r.3t-dibenzoyl-bicyclo[2.2.2]octene-⁽⁵⁾(102599-25-7)

Safety Data

• Hazardous Substances Data: 102599-25-7(Hazardous Substances Data)

Upstream product

• 959-28-4 1,4-diphenylbut-2-ene-1,4-dione 
• 959-27-3 (Z)-1,4-diphenylbut-2-ene-1,4-dione 
• 1165952-91-9 cyclohexa-1,3-diene 

Relevant articles and documents

Formation of Tetraacetal Oxa-Cages and Convex Oxa-Cages Ozonolysis of Bicyclooctenes

Tetraacetal oxa-cage compounds 5a and 5b and convex oxa-cage compounds 7a and 8a are synthesized in a short sequence.Ozonolysis of endo adducts 2a and 2b in dichloromethane at -78 deg C followed by reduction with dimethylsulfide gave tetraacetal oxa-cages 5a and 5b in 35percent yields respectively.Ozonolysis of 2a in dichloromethane at -78 deg C followed by treatment with triethylamine gave the convex oxa-cage 7a in 34percent yield.These results support an acid-base proton transfer between the final ozonides and the base.The reasons that these oxa-cage compounds formed in low yields are discussed.The synthesis of tetraacetal oxacage 14, possessing aromatic substitutents directly on the skeleton of the oxa-cage, is accomplished.Key Words: Tetraacetal oxa-cages; Convex oxa-cages; Ozonolysis; Bicyclooctenes.