1026639-32-6

Basic information

• Product Name: 6-Methyl-6-phenylselanyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone
• Synonyms: 6-Methyl-6-phenylselanyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone
• CAS NO: 1026639-32-6
• Molecular Weight: 375.413
• Mol File: 1026639-32-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-Methyl-6-phenylselanyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Methyl-6-phenylselanyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone(1026639-32-6)
• EPA Substance Registry System: 6-Methyl-6-phenylselanyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone(1026639-32-6)

Safety Data

• Hazardous Substances Data: 1026639-32-6(Hazardous Substances Data)

Upstream product

• 153582-11-7 tert-Butyl-dimethyl-((1S,6S)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]hept-1-ylmethoxy)-silane 
• 153582-12-8 2-(tert-butyl-dimethyl-silanyloxy)-1-(1,2,2-trimethyl-cyclopentyl)-ethanone 
• 179944-42-4 (1'S)-1-(1',2',2'-trimethylcyclopentyl)hexane-1,5-dione 
• 179944-43-5 (1'S)-3-(1',2',2'-trimethylcyclopentyl)-2-cyclohexen-1-one 
• 88794-46-1 (-)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-methanol 
• 472-20-8 β-cyclogeraniol 
• 79-77-6 (E)-β-ionone 
• 34837-55-3 Phenylselenyl bromide 

Downstream Products

• 38412-84-9 (-)-δ-cuparenol 

Relevant articles and documents

Enantioselective synthesis of cuparane sesquiterpenes. Synthesis of (-)-cuparene and (-)-δ-cuparenol

(-)-Cuparene and (-)-δ-cuparenol, two cuparane-type sesquiterpenoids, were synthesized from β-cyclogeraniol in 47% and 27% overall yield, respectively, using a Katsuki-Sharpless asymmetric epoxidation, a pinacollic rearrangement, and a Robinson annulation as key synthetic steps.