1027004-67-6

Basic information

• Product Name: cis-bis(isopropylamine)tetrachloroplatinum(IV)
• CAS NO: 1027004-67-6
• Molecular Weight: 455.114
• Mol File: 1027004-67-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-bis(isopropylamine)tetrachloroplatinum(IV)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-bis(isopropylamine)tetrachloroplatinum(IV)(1027004-67-6)
• EPA Substance Registry System: cis-bis(isopropylamine)tetrachloroplatinum(IV)(1027004-67-6)

Safety Data

• Hazardous Substances Data: 1027004-67-6(Hazardous Substances Data)

Upstream product

• 97101-54-7 Pt(II)(isopropylamine)2Cl₂ 
• 25478-67-5 tetraethylammonium tetrachloroaurate(III) 

Relevant articles and documents

Effects of Geometric Configuration and Steric Hindrance on Rates and Mechanisms of Oxidation of Diaminedichloroplatinum(II) Complexes by Tetrachloroaurate(III) Ions

The oxidation reactions of trans- and/or cis- by - in the presence of Cl have been kinetically investigated in acetonitrile (R=H,Me,Et,Prn,Pri,Bun,Bui,Bus,But,CH2But,CH2Ph, or cyclo-C6H11).The rate law for the oxidation of the trans complexes consists mainly of a third-order rate term, kc->->, whereas an additiona rate term, ka->->/(1+kb->), operates in the case of the cis complexes.A reaction scheme is proposed.The oxidation rates of both cis and trans complexes appear to be reduced by increasing the steric hindrance of the amine, cis complexes being more sensitive towards changes of steric hindrance than trans analogues.Approximate linear relationships correlate the reactivities (log k) of both cis and trans complexes with an amine steric hindrance parameter.