102804-62-6

Basic information

• Product Name: Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester
• CAS NO: 102804-62-6
• Molecular Formula: C11H15NO2
• Molecular Weight: 193.246
• Mol File: 102804-62-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester(102804-62-6)
• EPA Substance Registry System: Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester(102804-62-6)

Safety Data

• Hazardous Substances Data: 102804-62-6(Hazardous Substances Data)

Upstream product

• 111-24-0 1,5-dibromo-pentane 
• 13361-32-5 allyl cyanoacetate 

Downstream Products

• 1855-63-6 cyclohex-1-enecarbonitrile 
• 766-05-2 cyclohexane carbonitrile 

Relevant articles and documents

New Methods for the Syntheses of α,β-Unsaturated Ketones, Aldehydes, and Nitriles by the Palladium-Catalyzed Reactions of Allyl β-Oxo Esters, Allyl 1-Alkenyl Carbonates, and Allyl α-Cyano Esters

Allyl β-oxo esters, allyl 1-alkenyl carbonates, and allyl α-cyano esters are converted into α,β-unsaturated ketones, aldehydes, and nitriles by palladium-catalyzed intramolecular decarboxylation-dehydrogenation.Palladium-phosphine complexes such as Pd(OAc)2-PPh3, Pd(OAc)2-dppe, or Pd2(dba)3*CHCl3-PPh3, are effective catalysts.Yields depend on solvents and on the mole ratio of palladium to phosphine.The optimum Pd/P ratio for each substrate was determined.Use of nitriles as solvents is essential for the dehydrogenation.