1028295-36-4

Basic information

• Product Name: (E)-(2-fluoro-10-methoxycarbonyl-1-decenyl)(4-methylphenyl)iodonium fluoride
• Synonyms: (E)-(2-fluoro-10-methoxycarbonyl-1-decenyl)(4-methylphenyl)iodonium fluoride
• CAS NO: 1028295-36-4
• Molecular Weight: 452.323
• Mol File: 1028295-36-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-(2-fluoro-10-methoxycarbonyl-1-decenyl)(4-methylphenyl)iodonium fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(2-fluoro-10-methoxycarbonyl-1-decenyl)(4-methylphenyl)iodonium fluoride(1028295-36-4)
• EPA Substance Registry System: (E)-(2-fluoro-10-methoxycarbonyl-1-decenyl)(4-methylphenyl)iodonium fluoride(1028295-36-4)

Safety Data

• Hazardous Substances Data: 1028295-36-4(Hazardous Substances Data)

Upstream product

• 624-31-7 4-tolyl iodide 
• 2777-66-4 methyl 10-undecynoate 
• 371-11-9 4-(difluoroiodo)toluene 

Downstream Products

• 180071-98-1 1-(p-tolyl)-1-hexyne 

Relevant articles and documents

Stereo-and regio-selective addition of iodotoluene difluoride to alk-1-ynes. Selective synthesis of 2-fluoro-1-iodoalk-1-enes

p-Iodotoluene difluoride reacted with 1-alkynes to give trans adducts which could be converted to 2-fluoro-1-iodoalk-1-enes without isolation.

Stereoselective synthesis of (E)-1-fluoro-1,3-enynes

1-Fluoro-1,3-enynes were stereoselectively prepared by the cross-coupling reaction of 1-alkynes with β-fluoroalkenyliodides obtained from (β-fluoroalkenyl)iodonium salts. As the reaction proceeds under mild conditions, polyfunctionalized 1-fluoro-1,3-enyn

Stereoselective synthesis of (E)-β-fluoro-α,β-unsaturated esters by carbonylation of (E)-2-fluoro-1-iodo-1-alkenyliodonium salts

(E)-β-Fluoro-α,β-unsaturated esters were stereoselectively obtained by the palladium-catalyzed carbonylation reaction of (E)-2-fluoro-1-iodo-1-alkenyliodonium salts obtained by the addition of iodotoluene difluoride to 1-alkynes.