102969-01-7

Basic information

• Product Name: 2-methoxy-2-N-phenylimino-5,5-dimethyl-1,3,2-dioxaphosphorinane
• Synonyms: 2-methoxy-2-N-phenylimino-5,5-dimethyl-1,3,2-dioxaphosphorinane
• CAS NO: 102969-01-7
• Molecular Weight: 255.254
• Mol File: 102969-01-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-methoxy-2-N-phenylimino-5,5-dimethyl-1,3,2-dioxaphosphorinane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxy-2-N-phenylimino-5,5-dimethyl-1,3,2-dioxaphosphorinane(102969-01-7)
• EPA Substance Registry System: 2-methoxy-2-N-phenylimino-5,5-dimethyl-1,3,2-dioxaphosphorinane(102969-01-7)

Safety Data

• Hazardous Substances Data: 102969-01-7(Hazardous Substances Data)

Upstream product

• 1005-69-2 2-methoxy-5,5-dimethyl-1,3,2-dioxaphosphorinane 
• 622-37-7 Phenyl azide 

Downstream Products

• 132868-57-6 (2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinanyl)(O,O-diphenyl phosphoryl)oxide 
• 132868-58-7 (5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinanyl)(p-toluenesulphonyl)oxide 
• 4090-52-2 5,5,5',5'-tetramethyl-2,2'-oxy-bis-[1,3,2]dioxaphosphinane 2,2'-dioxide 
• 102969-25-5 6-Methoxy-3,3-dimethyl-7-phenyl-1,5-dioxa-7-aza-6λ⁵-phospha-spiro[5.5]undeca-8,10-diene-8,9,10,11-tetracarboxylic acid tetramethyl ester 
• 102969-26-6 10-Methoxy-3,3-dimethyl-7-phenyl-1,5-dioxa-7-aza-6λ⁵-phospha-spiro[5.5]undeca-6(11),8-diene-8,9,10,11-tetracarboxylic acid tetramethyl ester 
• 102969-07-3 2-(2-Methoxy-5,5-dimethyl-2λ⁵-[1,3,2]dioxaphosphinan-2-ylidene)-3-[(E)-phenylimino]-succinic acid dimethyl ester 
• 132868-54-3 2-N-benzoyl-N-phenylamino-2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinane 

Relevant articles and documents

Electrophilic catalysis of N-- > 0 phosphyl migration

2-N-Benzoyl-N-phenylamino-2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinane (3a) undergoes rearrangement to (2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinanyl) (N-phenyliminobenzoyl)oxide (4a). This transformation is shown to be catalysed by electrophilic reagents such as benzoyl chloride, trimethylsilyl chloride, p-toluenesulphonyl chloride.