103095-28-9

Basic information

• Product Name: 1-(2-methoxy-5-methyl-phenyl)-ethanone oxime
• Synonyms: 1-(2-methoxy-5-methyl-phenyl)-ethanone oxime
• CAS NO: 103095-28-9
• Molecular Weight: 179.219
• Mol File: 103095-28-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2-methoxy-5-methyl-phenyl)-ethanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-methoxy-5-methyl-phenyl)-ethanone oxime(103095-28-9)
• EPA Substance Registry System: 1-(2-methoxy-5-methyl-phenyl)-ethanone oxime(103095-28-9)

Safety Data

• Hazardous Substances Data: 103095-28-9(Hazardous Substances Data)

Upstream product

• 20628-07-3 2-acetyl-4-methylanisole 
• 104-93-8 p-methylanizole 

Downstream Products

• 104338-22-9 1-(2-methoxy-5-methyl-phenyl)-ethylamine 
• 20628-07-3 2-acetyl-4-methylanisole 
• 120-71-8 Cresidine 

Relevant articles and documents

Facile preparation of 5-alkyl-1-aryltetrazoles with arenes, acyl chlorides, hydroxylamine, and diphenylphosphoryl azide

Successive treatment of arenes with acyl chlorides and AlCl3, the addition of water and removal of solvent, the reaction with NH2OH?HCl and K2CO3, and the reaction with diphenylphosphoryl azide and DBU under warming conditions gave the corresponding 5-alkyl-1-aryltetrazoles efficiently in good to moderate yields. The present method is one-pot transformation of arenes into 5-alkyl-1-aryltetrazoles using the Friedel-Crafts acylation and the Beckmann rearrangement under transition-metal-free conditions.