1031416-82-6Relevant articles and documents
Iridium-catalyzed enantioselective formal [4+2] cycloaddition of biphenylene and alkynes for the construction of axial chirality
Shibata, Takanori,Nishizawa, Go,Endo, Kohei
, p. 765 - 768 (2008)
Chiral iridium complex catalyzed a formal [4+2] cycloaddition of biphenylene with disubstituted alkynes, which was initiated by carbon-carbon bond cleavage. Axially chiral 9,10-disubstituted phenanthrenes were enantiomerically obtained. Georg Thieme Verlag Stuttgart.