1032154-63-4Relevant articles and documents
Asymmetric ruthenium-catalyzed hydrogenation of 2- and 2,9-substituted 1,10-phenanthrolines
Wang, Tianli,Chen, Fei,Qin, Jie,He, Yan-Mei,Fan, Qing-Hua
supporting information, p. 7172 - 7176 (2013/07/26)
A 'Phen'atic: The title reaction proceeds in the presence of the chiral cationic ruthenium diamine catalyst (R,R)-1 (Tf=trifluoromethanesulfonyl, Ts=4-toluenesulfonyl). Both chiral 1,2,3,4-tetrahydro- and 1,2,3,4,7,8,9,10- octahydro-1,10- phenanthroline derivatives could be obtained in high yields with excellent enantio- and diastereoselectivity. Copyright