103216-74-6

Basic information

• Product Name: Cyclohex-1-enylmethyl-diethyl-borane
• Synonyms: Cyclohex-1-enylmethyl-diethyl-borane
• CAS NO: 103216-74-6
• Molecular Weight: 164.099
• Mol File: 103216-74-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohex-1-enylmethyl-diethyl-borane(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohex-1-enylmethyl-diethyl-borane(103216-74-6)
• EPA Substance Registry System: Cyclohex-1-enylmethyl-diethyl-borane(103216-74-6)

Safety Data

• Hazardous Substances Data: 103216-74-6(Hazardous Substances Data)

Upstream product

• 135305-28-1 K⁽¹⁺⁾*C₆H₉CH₂^(1-)=K(C₆H₉CH₂) 
• 5314-83-0 diethylchloroborane 
• 591-49-1 1-methylcyclohex-1-ene 
• 7440-09-7 potassium 
• 13294-23-0 bis(trimethylsilylmethyl)mercury 

Downstream Products

• 2047-97-4 2-methyl-1-acetyl-1-cyclohexene 
• 65756-02-7 2-methylenecyclohexyl methyl ketone 
• 54625-15-9 2-methylcyclohex-1-ene-1-carbaldehyde 
• 4845-04-9 1-cyclohexene-1-methanol 
• 79828-22-1 1-(2-Methylene-cyclohexyl)-ethanol 
• 78426-32-1 2-(hydroxymethyl)-1-methylenecyclohexane 

Relevant articles and documents

SYNTHESIS WITH ORGANOBORANES. I. SYNTHESIS OF ALLYLIC DIETHYLBORANES AND B-ALLYLIC BORINANES VIA METALATION OF OLEFINS. CONTRATHERMODYNAMIC ISOMERIZATION OF OLEFINS

Allylic organopotassium compounds prepared by metalation of olefins with trimethylsilylmethylpotassium reacted with chlorodiethylborane and b-chloroborinane to give allylic diethylboranes and B-allylic borinanes, respectively.Hydrolysis of these organoboranes proceeding with allylic rearrangement leads to isomerized olefins.In this way, (E,Z)-2-pentene, (Z)-2-heptene, 1-methylcyclohexene and (+)-α-pinene were cleanly transformed into 1-pentene, 1-heptene, methylenecyclohexane and (+)-β-pinene, respectively.Stereochemistry of the addition of myrtenyldiethylborane toformaldehyde and 2-cyclohexenyldiethylborane to 4-t-butylcyclohexanone is described.