103220-12-8

Basic information

• Product Name: Solvent Orange 86
• Synonyms: Solvent orange 86 (C.I. 58050)
• CAS NO: 103220-12-8
• Molecular Formula: C14H8O4
• Molecular Weight: 240.21092
• Mol File: 103220-12-8.mol
• Article Data: 55

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Solvent Orange 86(CAS DataBase Reference)
• NIST Chemistry Reference: Solvent Orange 86(103220-12-8)
• EPA Substance Registry System: Solvent Orange 86(103220-12-8)

Safety Data

• Hazardous Substances Data: 103220-12-8(Hazardous Substances Data)

Upstream product

• 108-31-6 maleic anhydride 
• 571-60-8 1,4-Dihydroxynaphthalene 
• 85-44-9 phthalic anhydride 
• 106-48-9 4-chloro-phenol 
• 123-31-9 hydroquinone 
• 1709-63-3 anthracene-1,4,9,10-tetraone 
• 74-90-8 hydrogen cyanide 
• 623-11-0 1-methyl-4-nitrosobenzene 
• 102442-71-7 3-benzoyl-1,4-dihydroxy-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid 
• 605-32-3 2-hydroxy-9,10-anthraquinone 
• 602-25-5 1,4-dichloroanthraquinone 
• 81-54-9 1,2,4-trihydroxy-9,10-anthraquinone 
• 82-44-0 1-chloroanthracene-9,10-dione 
• 2786-71-2 1-amino-4-anilino-9,10-dioxo-9,10-dihydro-anthracene-2-sulfonic acid 

Downstream Products

• 75829-97-9 1,4-Diethoxy-9,10-anthraquinone 
• 75300-11-7 1,4-bis-(3-hydroxymethyl-anilino)-anthraquinone 
• 81-47-0 1-hydroxy-4-(3-hydroxymethyl-anilino)-anthraquinone 
• 74440-71-4 1-hydroxy-4-(2,4,5-trimethyl-anilino)-anthraquinone 
• 70714-75-9 1,4-bis-(4-cyclohexyl-anilino)-anthraquinone 
• 119560-60-0 [4-(4-hydroxy-9,10-dioxo-9,10-dihydro-[1]anthrylamino)-phenyl]-acetonitrile 
• 5470-98-4 1,4-dihydroxy-9,10-dioxo-9,10-dihydro-anthracene-2,3-dicarbonitrile 
• 122924-85-0 9,10-diphenyl-9,10-dihydro-anthracene-1,4,9,10-tetraol 
• 60058-19-7 4,4'-(9,10-dioxo-9,10-dihydro-anthracene-1,4-diyldiamino)-bis-toluene-2-sulfonic acid 
• 1709-63-3 anthracene-1,4,9,10-tetraone 
• 21016-03-5 2-benzyl-1,4-dihydroxy-anthraquinone 
• 2289-36-3 1,4-diacetoxy-9,10-anthraquinone 
• 23861-69-0 1,4-dihydroxy-2-butyl-9,10-anthraquinone 
• 21016-06-8 1,4-dihydroxy-2-(4-methyl-benzyl)-anthraquinone 

Relevant articles and documents

Parimycin: Isolation and structure elucidation of a novel cytotoxic 2,3-dihydroquinizarin analogue of γ-indomycinone from a marine Streptomycete isolate

In our screening of actinomycetes from the marine environment for bioactive components, a new antibiotic with a novel structure designated as parimycin was obtained from the culture broth of Streptomyces sp. isolate B8652. The structure of the new antibiotic was determined by spectroscopic methods and by comparison of the NMR data with those of the structurally related γ-indomycinone.

One- and Two-electron Reduction of Quinizarin and 5-Methoxyquinizarin: A Pulse Radiolysis Study

Absorption characteristics of the semiquinone free radicals formed by one-electron reduction of quinizarin (QH2), 5-methoxyquinizarin (MQH2) and quinizarin 2-sulphonate (QSH2) have been studied by pulse radiolysis in a mixed solvent system consisting of water, isopropyl alcohol and acetone.Second-order rate constants have been determined for the reactions of (CH3)2COH with the quinones, of the semiquinone with O2 and of the semiquinones with each other.The one-electron reduction potentials (vs.NHE) are E17 = -269 mV for QH2, -333 mV for MQH2 and -298 mV for QSH2.They vary with pH in accordance with the pKa values of the parent quinones and the semiquinones.The radicals are stable within the approximate pH range 5-11.The stability constant is highest at pH 8.5 (Ks = 0.09) for QH2, at pH = 9.5 for QSH2 (Ks = 10) and pH = 10.8 for MQH2 (Ks = 4.8), respectively.The one-electron reduction potentials of the semiquinones and the two-electron reduction potentials of the quinones are calculated to be E27 = -188, -192 and -216 mV, and Em7 = -229, -263 and -257 mV for QH2, MQH2 and QSH2, respectively.The effect of solvent on the properties of the semiquinones is discussed.

Photochemical Hydroxylation of Anthracene-9,10-dione in Sulphuric Acid Solution

Near u.v. irradiation of anthracene-9,10-dione in deoxygenated 96percent H2SO4 generates the sulphate ester of 2-hydroxyanthracene-9,10-dione in high yield along with the 1-hydroxy isomer and the novel reduction products anthracen-9(10H)-one and 9,9'-bianthracene-10,10'(9H,9'H)-dione; contrary to previous results, the product distribution and the rate of reaction are dependent upon the concentration of O2 in the solution.

Combined spectral experiment and theoretical calculation to study the interaction of 1,4-dihydroxyanthraquinone for metal ions in solution

The interaction between 1,4-dihydroxyanthraquinone (1,4-DHA) and metal ions was studied by UV-Visible and fluorescence spectroscopies in solution. Time-dependent density functional theory calculations confirmed complex structures. The investigation results showed 1,4-DHA can selectively respond some metal ions and can be monitored by UV-Vis, fluorescence spectra and naked-eye. So 1,4-DHA has a potential application in the design of metal ions probe. More, as typical metal ions, Hg2+ and Er3+, their reaction abilities for 1,4-DHA were studied in detailed. Experimental results showed they have better response for 1,4-DHA. And theoretical calculation concluded that Er3+ easily reacts with 1,4-DHA over Hg2+ attributed to the low reaction energy of Er3+-1,4-DHA than Hg 2+-1,4-DHA.

Thermodynamics of semiquinone disproportionation in aqueous buffer

The thermodynamic parameters, Kdisp, ΔH° and ΔS°, controlling the disproportionation of semiquinones derived from 1,4-benzoquinone (BQ), 1,4-naphthoquinone (NQ), 2-methylbenzoquinone (MBQ), menadione (MNQ), naphthazarin (NZQ) and quinizarin (QNZ), have been determined. Smaller disproportionation constants, Kdisp, are observed upon addition of a fused benzene ring to the semiquinone structure. Negative enthalpies and positive entropies of disproportionation govern the disproportionation equilibria. Addition of OH groups to the 5 and 8 positions in NQ?- displaces the disproportionation equilibrium to the semiquinone probably due to intramolecular hydrogen bonding.

Visible-light photocatalytic activity of chitosan/polyaniline/CdS nanocomposite: Kinetic studies and artificial neural network modeling

Chitosan/polyaniline (CS/PAni), chitosan/CdS (CS/CdS) and chitosan/polyaniline/CdS nanocomposite were synthesized and characterized using X-ray diffraction pattern analysis, FT-IR spectroscopy and scanning electronic microscopy. The adsorption performance and photocatalytic activity of CS/PAni/CdS was compared with CS/PAni and CS/CdS in the removal of Reactive Blue 19 (RB19) dye. After five cycles of experiments under visible light irradiation, CS/PAni/CdS retained high photocatalytic activity which confirmed good stability of nanocomposite. Moreover, the kinetics of decolorization was investigated and novel equation rate for dye removal was established by considering two parallel mechanisms including adsorption and surface photocatalytic degradation of dye by CS/PAni/CdS. Artificial neural network was employed to develop a model for predicting the decolorization efficiency and determining the relative importance of operational parameters. A 3-layer perceptron network with optimized 5:10:1 topology could provide adequate predictive performance (R2 = 0.983). Moreover, the photocatalytic degradation of RB19 was monitored by measuring the total organic carbon (TOC) and GC-MS analysis, enabling the evaluating the mineralization and identifying the intermediates. During 120 min of experiment, more than 80% of TOC was removed.

Oxidative Coupling of Furans and Naphthoquinones: a Potential Route to Anthracyclinones

2-Furyl-1,4-naphthoquinones have been prepared by treatment of mixtures of furans and naphthoquinones with chloranil and other oxidants, and used to synthesize quinizarin and 6,11-dihydroxynaphthacene-5,12-dione in a reaction sequence which promises great versatility.

Synthesis method of orange intermediate

The invention discloses a synthesis method of an orange intermediate, and belongs to the field of orange intermediates. The synthesis method of the orange intermediate comprises the following steps: 1, preparing 106-110% sulfuric acid as a solvent; 2, adding p-chlorophenol and excessive phthalic anhydride into a clean reaction container, adding a catalyst boric anhydride, and pouring the sulfuricacid solvent obtained in step 1 into the reaction container; 3, heating the reaction container to 190-200 DEG C, and reacting the p-chlorophenol and phthalic anhydride added in step 2 under the actionof a catalyst; and 4, after the reaction is finished, cooling, diluting, separating out upper wastewater, and filtering to obtain the orange intermediate. According to the scheme, 106-110% sulfuric acid is adopted as the solvent, boric anhydride is adopted as the catalyst, and hydrolysis of phthalic anhydride can be greatly reduced, so the use amount of phthalic anhydride is reduced, the yield isgreatly increased, phthalic anhydride is recycled, and COD of three wastes is greatly reduced.

Fluorescent molecule for recognizing copper ions, preparation method and application

The invention discloses a fluorescent molecule for recognizing copper ions, a preparation method and application. Polycyclic aromatic hydrocarbons such as naphthalene rings or anthracene rings are used as initial raw materials; through a series of optimized organic synthesis reaction (substitution and addition), after the connection with different recognition sites, molecular clamp body tweezer host compounds with different recognition performance can be obtained. The fluorescent molecule can be used for copper ion detection and solves the problems that the existing molecule device is difficult to effectively recognize object molecules.