103334-80-1

Basic information

• Product Name: [(Au(P(C₆H₄OCH₃)3))2(CC)]
• CAS NO: 103334-80-1
• Molecular Weight: 1122.69
• Mol File: 103334-80-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(Au(P(C₆H₄OCH₃)3))2(CC)](CAS DataBase Reference)
• NIST Chemistry Reference: [(Au(P(C₆H₄OCH₃)3))2(CC)](103334-80-1)
• EPA Substance Registry System: [(Au(P(C₆H₄OCH₃)3))2(CC)](103334-80-1)

Safety Data

• Hazardous Substances Data: 103334-80-1(Hazardous Substances Data)

Upstream product

• 96029-36-6 chloro[tris(para-methoxyphenyl)phosphine]gold(I) 
• 74-86-2 acetylene 

Relevant articles and documents

Preparation and Ligand-exchange Reactions of Phosphinegold Ethynyl Complexes

Phosphinegold chlorides, , react readily with terminal alkynes RC*CH in ethanolic sodium ethoxide to produce high yields of ethynyl complexes .When R = H a second reaction leads to formation of .In a similar manner, the cyclopentadienyl complex can conveniently be made from , Na(OEt), and C5H6.The phosphine of rapidly exchanges in solutions with free phosphines.The compounds and > readily equilibrate with and >, a reaction which could also involve exchange of phosphines, but the exchange of Cl for C*CPh is another possible pathway.Phenylethynyl groups from exchange with both chlorides of HgCl2, cis-, and cis-.With the latter complex the exchange is non-stereospecific, unlike related reactions with organomercurials.