103348-78-3

Basic information

• Product Name: 2-(4-methoxyphenyl)hexahydrooxepine
• Synonyms: 2-(4-methoxyphenyl)hexahydrooxepine
• CAS NO: 103348-78-3
• Molecular Weight: 206.285
• Mol File: 103348-78-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxyphenyl)hexahydrooxepine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxyphenyl)hexahydrooxepine(103348-78-3)
• EPA Substance Registry System: 2-(4-methoxyphenyl)hexahydrooxepine(103348-78-3)

Safety Data

• Hazardous Substances Data: 103348-78-3(Hazardous Substances Data)

Upstream product

• 149109-19-3 1-(4-methoxyphenyl)hexane-1,6-diol 
• 541507-46-4 1-(1-(allyloxy)pent-4-en-1-yl)-4-methoxybenzene 
• 113579-77-4 1-(4-methoxy-phenyl)-pent-4-en-1-ol 
• 52244-70-9 4-(4-methoxyphenyl)butan-1-ol 
• 80174-16-9 1-(4’-methoxyphenyl)butan-1,4-diol 
• 24165-60-4 1-(4-methoxyphenyl)but-3-en-1-ol 
• 123-11-5 4-methoxy-benzaldehyde 
• 821-41-0 5-Hexen-1-ol 
• 70744-47-7 (p-methoxyphenyl)tri-n-butylstannane 

Relevant articles and documents

A mild method for generation of p-methoxybenzyl cation through NIS- mediated activation of p-methoxybenzyl 4-pentenyl ether

A mild and facile method for generation of p-methoxybenzyl cation through NIS-mediated activation of p-methoxybenzyl 4-pentenyl ether was achieved. Under the present activation conditions, various alcohols were convened to the corresponding p-methoxybenzyl ethers. A scope and limitation of the present p-methoxybenzylation reaction was also investigated.

Heterocyclization involving benzylic C(sp3)-H functionalization enabled by visible light photoredox catalysis

A general and efficient method for heterocyclization involving benzylic C(sp3)-H functionalization enabled by visible light photoredox catalysis to access a wide range of structurally diverse oxygen as well as nitrogen heterocycles up to a gram scale is reported. The potential application of this new methodology is demonstrated by the total synthesis of (-)-codonopsinine and (+)-centrolobine. Herein it is proposed that selectfluor, unlike a fluorinating reagent, acts as an oxidative quencher and a hydrogen radical acceptor.

PdII-katalysierte regioselektive Arylchlorierung und Oxyarylierung ungesaettigter Alkohole

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