103549-35-5

Basic information

• Product Name: methyl 3-chlorotricyclo[3.3.1.1~3,7~]decane-1-carboxylate
• CAS NO: 103549-35-5
• Molecular Formula: C₁₂H₁₇ClO₂
• Molecular Weight: 228.7152
• Mol File: 103549-35-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 292.3°C at 760 mmHg
• Flash Point: 138.2°C
• Density: 1.22g/cm³
• Vapor Pressure: 0.00185mmHg at 25°C
• Refractive Index: 1.532
• CAS DataBase Reference: methyl 3-chlorotricyclo[3.3.1.1~3,7~]decane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-chlorotricyclo[3.3.1.1~3,7~]decane-1-carboxylate(103549-35-5)
• EPA Substance Registry System: methyl 3-chlorotricyclo[3.3.1.1~3,7~]decane-1-carboxylate(103549-35-5)

Safety Data

• Hazardous Substances Data: 103549-35-5(Hazardous Substances Data)

Upstream product

• 711-01-3 methyl adamantane-1-carboxylate 
• 21816-08-0 3-bromoadamantane-1-carboxylic acid 
• 27983-08-0 bromo-3 adamantylcarboxylate de methyle 
• 55339-64-5 2,4-dimethyl-3-trimethylsilyloxy-2-pentene 

Relevant articles and documents

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Synthese de quelques structures encombrees derivees de l'adamantane et de ses analogues par alkylation des ether d'enol trimethylsilyliques

Alkylation of trimethylsilyl enol ethers of 2,4-dimethyl-3-pentanone, cyclopentanone and cyclohexanone has been extended to alkylating agents with a cage structure (substituted or functionalized adamantyl, diamantyl, homoadamantyl and noradamantyl chlorides or bromides).This method affords some new cage structured aliphatic and alicyclic ketones.In some cases one observes a new TiCl4 promoted reaction where the bromine in the alkylating agent is replaced by chlorine.This work is a generalization of our previous extended studies on α-alkylation of ketones with tertiary alkylating agents.