103660-90-8

Basic information

• Product Name: ((R)-1-Phenyl-ethyl)-carbamic acid (R)-1-phenyl-allyl ester
• CAS NO: 103660-90-8
• Molecular Weight: 281.354
• Mol File: 103660-90-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((R)-1-Phenyl-ethyl)-carbamic acid (R)-1-phenyl-allyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: ((R)-1-Phenyl-ethyl)-carbamic acid (R)-1-phenyl-allyl ester(103660-90-8)
• EPA Substance Registry System: ((R)-1-Phenyl-ethyl)-carbamic acid (R)-1-phenyl-allyl ester(103660-90-8)

Safety Data

• Hazardous Substances Data: 103660-90-8(Hazardous Substances Data)

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 69562-10-3 1-phenyl-3-phenylseleno-1-propene 
• 104713-12-4 (R)-1-phenylprop-2-en-1-ol 
• 33375-06-3 (1R)-1-phenylethyl isocyanate 
• 4393-06-0 1-Phenyl-2-propen-1-ol 

Relevant articles and documents

ASYMMETRIC OXIDATION OF ACHIRAL SELENIDES TO OPTICALLY ACTIVE SELENOXIDES. STEREOCHEMISTRY OF THE ALLYL SELENOXIDE-SELENENATE SIGMATROPIC REARRANGEMENT

Asymmetric oxidation of methyl phenyl selenide (3), under anhydrous conditions, by chiral 2-sulfonyloxaziridines, 1-2, give optically active methyl phenyl selenoxide (8.1-9.3percent ee).The stereochemistry of the selenoxide is determined by the configuration of the oxaziridine three membered ring with nonbonded steric interactions responsible for the chiral recognition.Asymmetric oxidation of E-phenyl cinnamyl selenide (7) by 1-2 affords optically active 1-phenylallyl alcohol (9).A concerted sigmatropic rearrangement via an exo transition state is proposed.