1036648-27-7Relevant articles and documents
Construction of Esters through Sulfuryl Fluoride (SO 2 F 2) Mediated Dehydrative Coupling of Carboxylic Acids with Alcohols at Room Temperature
Qin, Hua-Li,S Alharbi, Njud,Wang, Shi-Meng
, p. 3901 - 3907 (2019/10/11)
A facile method for the construction of esters through dehydrative coupling of carboxylic acids with alcohols is developed. The reactions are mediated by sulfuryl fluoride (SO 2 F 2) at room temperature and proceed with high efficiency. The method has several advantages including broad substrate scope, mild conditions, excellent functional group compatibility and affords high yields, even on gram scale.
Organic electrosynthesis using toluates as simple and versatile radical precursors
Lam, Kevin,Marko, Istvan E.
supporting information; experimental part, p. 95 - 97 (2009/03/11)
The electrolysis of toluate esters leads smoothly to the formation of the radical of the alkyl fragment. This property has been used to develop a new electrochemical deoxygenation reaction. The Royal Society of Chemistry.
Toluates: unexpectedly versatile reagents
Lam, Kevin,Markó, István E.
supporting information; experimental part, p. 10930 - 10940 (2010/02/28)
The mechanism of the monoelectronic reduction of aromatic esters has been investigated. The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and the allylation of ketones is also reported. Finally, the use of aromatic esters as robust, though easily removable, protecting groups is depicted.