103702-75-6

Basic information

• Product Name: allyl α-D-arabinofuranoside
• Synonyms: allyl α-D-arabinofuranoside
• CAS NO: 103702-75-6
• Molecular Weight: 190.196
• Mol File: 103702-75-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: allyl α-D-arabinofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl α-D-arabinofuranoside(103702-75-6)
• EPA Substance Registry System: allyl α-D-arabinofuranoside(103702-75-6)

Safety Data

• Hazardous Substances Data: 103702-75-6(Hazardous Substances Data)

Upstream product

• 532-20-7 L-arabinose 
• 107-18-6 allyl alcohol 
• 532-20-7 D-Ribose 
• 58-86-6 D-xylose 
• 532-20-7 D-arabinofuranose 
• 10323-20-3 D-Arabinose 
• 50-69-1 D-ribose 
• 106-95-6 allyl bromide 
• 5328-37-0 L-arabinose 

Downstream Products

• 103702-76-7 allyl 5-O-trityl-D-arabinofuranoside 
• 1431388-88-3 allyl 2,3-anhydro-5-O-benzoyl-α-D-lyxofuranoside 
• 1431388-85-0 N-acetyl-2,3-aziridino-5-O-benzoyl-2,3-dideoxy-d-ribofuranose 
• 1431388-86-1 N-acetyl-2,3-aziridino-5-O-benzoyl-2,3-dideoxy-d-ribofuranose 
• 1431388-84-9 allyl N-acetyl-2,3-aziridino-5-O-benzoyl-2,3-dideoxy-α-D-ribofuranoside 
• 1431388-92-9 allyl 3-azido-5-O-benzoyl-3-deoxy-2-O-p-toluenesulfonyl-α-D-arabinofuranoside 
• 1431388-91-8 allyl 3-azido-5-O-benzoyl-3-deoxy-α-D-arabinofuranoside 
• 934822-33-0 allyl 3-nitro-3-deoxy-6-O-tosyl-β-D-glucopyranoside 
• 134149-36-3 prop-1-enyl 2,3,5-tri-O-benzyl-α,β-L-arabinofuranoside 

Relevant articles and documents

Green glycosylation promoted by reusable biomass carbonaceous solid acid: An easy access to β-stereoselective terpene galactosides

An efficient green protocol has been developed for the atom economic glycosylation of unprotected, unactivated glycosyl donors and glycosylation of glycosyl trichloroacetimidates with the aid of reusable eco-friendly biomass carbonaceous solid acid as catalyst. The Royal Society of Chemistry.

Anomeric alkylations and acylations of unprotected mono- and disaccharides mediated by pyridoneimine in aqueous solutions

A site-specific deprotonation followed by alkylations and acylations of sugar hemiacetals to the corresponding alkyl glycosides and acylated sugars in aqueous solutions is disclosed herein. Pyridoneimine as a new base is developed to mediate the deprotonation of readily available sugar hemiacetals and further reactions with alkylation and acylation agents.

Synthesis of the spirastrellolide A, B/C spiroketal: Enabling solutions for problematic au(I)-catalyzed spiroketalizations

A synthesis of the spirastrellolide A, B/C-ring monounsaturated spiroketal is reported. The key step relies on a Au-catalyzed spiroketalization of a propargyl triol employing an acetonide as a regioselectivity regulator. Through observation and analysis, a set of conditions has been developed that facilitates the use of a mixture of diastereomeric substrates, obviating the need to control the stereochemistry of the propargyl stereocenter and enabling a convenient retrosynthetic disconnection. The key reaction proceeds in 80% yield in 1 min at ambient temperature with the Me3PAuCl/AgOTf catalyst system. These conditions should be widely applicable for new synthetic endeavors as they appear to overcome all issues with the Au-catalyzed spiroketalization.