103796-14-1

Basic information

• Product Name: 5-(acetylamino)-2-methylphenylacetate
• Synonyms: 5-(acetylamino)-2-methylphenylacetate
• CAS NO: 103796-14-1
• Molecular Formula: C₁₁H₁₃NO₃
• Molecular Weight: 207.22582
• Mol File: 103796-14-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-(acetylamino)-2-methylphenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(acetylamino)-2-methylphenylacetate(103796-14-1)
• EPA Substance Registry System: 5-(acetylamino)-2-methylphenylacetate(103796-14-1)

Safety Data

• Hazardous Substances Data: 103796-14-1(Hazardous Substances Data)

Upstream product

• 2835-95-2 amino-4 hydroxy-2 toluene 
• 108-24-7 acetic anhydride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 103-89-9 4-Methylacetanilide 
• 1189747-13-4 C₇H₁₁NO₂ 
• 64-19-7 acetic acid 

Downstream Products

• 5307-07-3 3-hydroxy-4-methylacetanilide 

Relevant articles and documents

Direct acetoxylation and etherification of anilides using phenyliodine bis(trifluoroacetate)

Treatment of various anilides with 1.5 equiv. of phenyliodine bis(trifluoroacetate) (PIFA) and 1.0 equiv. of BF3·OEt 2 in AcOH at room temperature afforded the corresponding para-acetoxylated products with high regioselectivity. In addition, this reaction could be expanded to the etherification of anilides. In the presence of 2.0 equiv. of PIFA and 2.0 equiv. of BF3·OEt2, the reaction of anilides with alcohols provided the corresponding para-etherified products in good yields. The Royal Society of Chemistry 2011.