103816-91-7

Basic information

• Product Name: dicarbonyl[1-4-η-5-(1,3-dihydroxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron
• CAS NO: 103816-91-7
• Molecular Weight: 590.393
• Mol File: 103816-91-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dicarbonyl[1-4-η-5-(1,3-dihydroxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron(CAS DataBase Reference)
• NIST Chemistry Reference: dicarbonyl[1-4-η-5-(1,3-dihydroxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron(103816-91-7)
• EPA Substance Registry System: dicarbonyl[1-4-η-5-(1,3-dihydroxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron(103816-91-7)

Safety Data

• Hazardous Substances Data: 103816-91-7(Hazardous Substances Data)

Upstream product

• 85939-52-2 Fe(CO)2(P(OC₆H₅)3)(C₇H₉(CH(OOCCH₃)2)) 
• 1191-15-7 diisobutylaluminium hydride 
• 16853-85-3 lithium aluminium tetrahydride 

Downstream Products

• 103816-96-2 Fe(CO)2(P(OC₆H₅)3)(C₇H₈(CH(CH₂OH)CH₂O)) 
• 103834-75-9 dicarbonyl[1-4-η-5-(1,3-diacetoxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron 

Relevant articles and documents

Stereocontrolled double functionalization of (cyclohexadiene)- and (cycloheptadiene)iron complexes via oxidative cyclization techniques

Oxidative cyclization of primary alcohol groups onto diene-Fe(CO)2L systems in six- and seven-membered rings has been investigated by using a variety of oxidizing agents and various substituents on the diene. The product cyclic ethers, e.g., complexes 6,17, and 18, are readily opened on treatment with tetrafluoroboric acid in the presence of acetic anhydride to give stereospecifically substituted dienyl-Fe(CO)2L complexes 7 and 16. Nucleophilic addition to these latter complexes occurs stereo- and regiospecifically, allowing access to cis 1,2-disubstitution in the six-membered ring and cis 1,3-disubstitution in the seven-membered ring.