103850-58-4

Basic information

• Product Name: 2-(adamant-1-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl) propane
• CAS NO: 103850-58-4
• Molecular Weight: 427.632
• Mol File: 103850-58-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(adamant-1-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl) propane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(adamant-1-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl) propane(103850-58-4)
• EPA Substance Registry System: 2-(adamant-1-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl) propane(103850-58-4)

Safety Data

• Hazardous Substances Data: 103850-58-4(Hazardous Substances Data)

Upstream product

• 28691-72-7 (E)-1-propenyl phenyl sulfone 
• 91233-19-1 1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione 
• 1121-30-8 1-hydroxy-2(1H)-pyridinethione 
• 28975-80-6 Phenyl-propenyl-sulfon 

Relevant articles and documents

Radical decarboxylative alkylation of tartaric acid

New derivatives of L-(+)-tartaric acid have been synthesized from the monomethyl-2,3-O-isopropylidene (R,R)-(+)-tartrate by visible light photolysis of its N-hydroxy-2-thiopyridone ester derivative in presence of activate alkenes. The carbon radical generated at the dioxolane ring adds stereoselectively to olefins to give the addition products with retention of configuration.

RADICAL ADDITION TO VINYL SULPHONES AND VINYL PHOSPHONIUM SALTS

Alkyl radicals, derived from decarboxylation of carboxylic acids, add readily to phenyl vinyl sulphone and vinyl phosphonium bromide.The adducts may be further converted into a variety of useful synthetic intermediates.