103850-59-5

Basic information

• Product Name: (1,2-bis{(diphenylphosphino)methyl}benzene)dichloropalladium(II)
• CAS NO: 103850-59-5
• Molecular Weight: 651.848
• Mol File: 103850-59-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1,2-bis{(diphenylphosphino)methyl}benzene)dichloropalladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (1,2-bis{(diphenylphosphino)methyl}benzene)dichloropalladium(II)(103850-59-5)
• EPA Substance Registry System: (1,2-bis{(diphenylphosphino)methyl}benzene)dichloropalladium(II)(103850-59-5)

Safety Data

• Hazardous Substances Data: 103850-59-5(Hazardous Substances Data)

Upstream product

• 21264-30-2 dichloro bis(acetonitrile) palladium(II) 
• 62144-65-4 1,2-bis((diphenylphosphino)methyl)benzene 

Downstream Products

• 1359746-74-9 (1,1-dicyanoethylene-2,2-dithiolate)Pd(1,2-C₆H₄(CH₂PCy₂)2) 
• 1027105-00-5 [Pd(SH)2(o-bis(diphenylphosphinomethyl)benzene)] 
• 132779-76-1 (1,2-bis{(diphenylphosphino)methyl}benzene)dibromopalladium(II) 
• 132779-77-2 (1,2-bis{(diphenylphosphino)methyl}benzene)diiodopalladium(II) 

Relevant articles and documents

209. The Coordination Chemistry of 1,2-Bisbenzene with Nickel(II), Palladium(II), Platinum(II), and Platinum(0) and the X-Ray Crystals Structure of benzene)(C2H4)>

The preparation of complexes (M = Ni, Pd, and Pt; X = Cl, Br, and I; 1 = 1,2-bisbenzene), , (alkene = C2H4 and CH2 = CHCN), and is reported.Their 1H- and 31P-NMR spectra were recorded and used for structural assignments.The X-ray crystal structure of was determined.It is shown that the P-Pt-P bond angle in this complex differs significantly from those found in related compounds with monodentate phosphines, and that this difference is likely to be due to intramolecular contacts.