103884-34-0

Basic information

• Product Name: 1-METHYLCYCLOHEXYLFORMATE
• Synonyms: 1-METHYLCYCLOHEXYLFORMATE
• CAS NO: 103884-34-0
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 0
• Mol File: 103884-34-0.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-METHYLCYCLOHEXYLFORMATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-METHYLCYCLOHEXYLFORMATE(103884-34-0)
• EPA Substance Registry System: 1-METHYLCYCLOHEXYLFORMATE(103884-34-0)

Safety Data

• Hazardous Substances Data: 103884-34-0(Hazardous Substances Data)

Upstream product

• 590-67-0 1-Methylcyclohexanol 
• 100-07-2 4-methoxy-benzoyl chloride 
• 64-18-6 formic acid 
• 67-56-1 methanol 

Downstream Products

• 64-18-6 formic acid 
• 590-67-0 1-Methylcyclohexanol 

Relevant articles and documents

-

-

IRON-CATALYZED CROSS-COUPLING OF METHHANOL WITH SECONDARY OR TERTIARY ALCOHOLS TO PRODUCE FORMATE ESTERS

A process for preparing a variety of secondary and tertiary alkyl formate esters via the coupling of methanol and secondary (or tertiary) alcohols. Iron-based catalysts, supported by pincer ligands, are employed to produce these formate esters in high yields and unprecedentedly high selectivities (>99%). Remarkably, the coupling strategy is also applicable to bulkier tertiary alcohols, which afford corresponding tertiary formate esters in moderately high yields and high selectivities.

Phase-Managed Organic Synthesis. A New Synthesis of Mixed Formic Anhydrides

Two new mixed formic anhydrides, cinnamic formic anhydride and formic 4-methoxybenzoic anhydride, can be prepared in high yield ( c.a. 80percent) from equimolar mixtures of sodium formate and the appropriate acid chloride with a solid-phase copolymer of pyridine 1-oxide as catalyst, and they exhibit excellent selectivity as formylating agents of alcohols and amines