1038860-88-6

Basic information

• Product Name: 5-[1-(2-oxopropyl)cyclohexyl]furan-2(5H)-one
• Synonyms: 5-[1-(2-oxopropyl)cyclohexyl]furan-2(5H)-one
• CAS NO: 1038860-88-6
• Molecular Weight: 222.284
• Mol File: 1038860-88-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-[1-(2-oxopropyl)cyclohexyl]furan-2(5H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-[1-(2-oxopropyl)cyclohexyl]furan-2(5H)-one(1038860-88-6)
• EPA Substance Registry System: 5-[1-(2-oxopropyl)cyclohexyl]furan-2(5H)-one(1038860-88-6)

Safety Data

• Hazardous Substances Data: 1038860-88-6(Hazardous Substances Data)

Upstream product

• 874-68-0 1-cyclohexylidene-2-propanone 
• 121896-38-6 2-tert-butyldimethylsilyloxyfuran 

Relevant articles and documents

Highly effective vinylogous Mukaiyama-Michael reaction catalyzed by silyl methide species generated from 1,1,3,3-tetrakis(trifluoromethanesulfonyl)propane

(Chemical Equation Presented) Silyl methide species in situ generated from 1,1,3,3-tetrakis(trifluoromethanesulfonyl)propane (Tf2CHCH 2CHTf2) performed as an excellent acid catalyst for the vinylogousMukaiyama-Michael reaction of α,β-unsaturated ketones with 2-silyloxyfurans. Notably, the required loading of Tf2CHCH 2CHTf2 to obtain the 1,4-adducts in reasonable yield was significantly low (from 0.05 to 1.0 mol%). This carbon acid-mediatedVMMreaction provides a powerful synthetic methodology to construct highly substituted γ-butenolide structure. 2010 American Chemical Society.