1038996-87-0

Basic information

• Product Name: E-styrylsulfonylacetic acid methyl ester
• Synonyms: E-styrylsulfonylacetic acid methyl ester
• CAS NO: 1038996-87-0
• Molecular Weight: 240.28
• Mol File: 1038996-87-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: E-styrylsulfonylacetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: E-styrylsulfonylacetic acid methyl ester(1038996-87-0)
• EPA Substance Registry System: E-styrylsulfonylacetic acid methyl ester(1038996-87-0)

Safety Data

• Hazardous Substances Data: 1038996-87-0(Hazardous Substances Data)

Upstream product

• 6783-05-7 trans-2-phenylvinylboronic acid 
• 96-32-2 bromoacetic acid methyl ester 
• 67-56-1 methanol 
• 137325-91-8 (Z)-styrylsulfonyl acetic acid 
• 100-42-5 styrene 
• 1312689-83-0 methyl {[(diethoxyphosphoryl)methyl]sulfonyl}acetate 
• 100-52-7 benzaldehyde 

Downstream Products

• 1339152-10-1 2-(4,5-dihydro-4-phenyl-1H-pyrazol-3-ylsulfonylmethyl)-4,5-dihydro-oxazole 
• 1339152-17-8 2-(4,5-dihydro-4-phenyl-1H-pyrazol-3-ylsulfonylmethyl)-4,5-dihydro-thiazole 
• 1339152-21-4 2-(4,5-dihydro-1,3,5-triphenylpyrazol-4-ylsulfonylmethyl)-4,5-dihydrooxazole 
• 1339152-27-0 2-(4,5-dihydro-1,3,5-triphenylpyrazol-4-ylsulfonylmethyl)-4,5-dihydrothiazole 
• 1339152-34-9 2-(4,5-dihydro-3,5-diphenylisoxazol-4-ylsulfonylmethyl)-4,5-dihydro-oxazole 
• 1339152-41-8 2-(4,5-dihydro-3,5-diphenylisoxazol-4-ylsulfonylmethyl)-4,5-dihydro-thiazole 
• 1339152-46-3 2-(4-phenyl-1H-pyrazol-3-ylsulfonylmethyl)-4,5-dihydrooxazole 
• 1339152-52-1 2-(4-phenyl-1H-pyrazol-3-ylsulfonylmethyl)-4,5-dihydrothiazole 
• 1339152-58-7 2-(1,3,5-triphenylpyrazol-4-ylsulfonylmethyl)-4,5-dihydrooxazole 
• 1339152-65-6 2-(1,3,5-triphenylpyrazol-4-ylsulfonylmethyl)-4,5-dihydrothiazole 
• 1339152-69-0 2-(3,5-diphenylisoxazol-4-ylsulfonylmethyl)-4,5-dihydrooxazole 
• 1339152-76-9 2-(diphenylisoxazol-4-ylsulfonylmethyl)-4,5-dihydrothiazole 
• 1339152-83-8 2-(2-phenylethenesulfonylmethyl)-4,5-dihydrooxazole 
• 1339152-89-4 2-(2-phenylethenesulfonylmethyl)-4,5-dihydrothiazole 

Relevant articles and documents

Synthesis of Sulfones via Ru(II)-Catalyzed Sulfination of Boronic Acids

Ruthenium(II) complexes catalyze the insertion of sulfur dioxide into (het)aryl and alkenyl boronic acids. The transmetalation-sulfination process proceeds with DABSO in the presence of 5 mol % RuCl2(PPh3)3 in methanol at 100 °C. The intermediate sulfinate salt can be quenched with various electrophiles such as alkyl halides, epoxides, Michael acceptors, and λ3-iodanes in moderate to good yields. The reported sulfone synthesis can be performed either as a direct one-pot or one-pot two-step procedure depending on the reactivity of the electrophile.

A new method for the preparation of (E)-2-(styrylsulfonyl)acetic acid esters and their reactions with hydrazine hydrate

A new route to esters of (E)-2-(styrylsulfonyl)acetic acid has been developed. Treatment of the methyl ester with hydrazine hydrate gave the six-membered 4-amino-5-phenylthiomorpholine-3-one 1,1-dioxide (1), and not the seven-membered 6-phenyl-1,4,5-thiad