103932-33-8

Basic information

• Product Name: Os{PCO(CF₃)}(CO)2(P(C₆H₅)3)2
• Synonyms: Os{PCO(CF₃)}(CO)2(P(C₆H₅)3)2
• CAS NO: 103932-33-8
• Molecular Weight: 898.793
• Mol File: 103932-33-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Os{PCO(CF₃)}(CO)2(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Os{PCO(CF₃)}(CO)2(P(C₆H₅)3)2(103932-33-8)
• EPA Substance Registry System: Os{PCO(CF₃)}(CO)2(P(C₆H₅)3)2(103932-33-8)

Safety Data

• Hazardous Substances Data: 103932-33-8(Hazardous Substances Data)

Upstream product

• 103932-34-9 [OsCl(PHCOCF₃)(CO)2(P(C₆H₅)3)2] 
• 131077-15-1 osmium(η1-OC(O)Me){PH(C(O)CF3)}(CO)2(PPh3)2 
• 7646-69-7 sodium hydride 
• 103932-34-9 OsCl{PHCO(CF₃)}(CO)2(P(C₆H₅)3)2 

Downstream Products

• 103932-29-2 [Os(AuI)(PCOCF₃)(CO)2(P(C₆H₅)3)2] 
• 13463-40-6 iron pentacarbonyl 
• 103932-30-5 OsI{PCH₃CO(CF₃)}(CO)2(P(C₆H₅)3)2 
• 103932-37-2 {OsCl(PH₃)(CO)2(P(C₆H₅)3)2}⁽¹⁺⁾*ClO₄^(1-) = {OsCl(PH₃)(CO)2(P(C₆H₅)3)2}ClO₄ 
• 103932-34-9 [OsCl(PHCOCF₃)(CO)2(P(C₆H₅)3)2] 

Relevant articles and documents

Organotransition metal substituted primary phosphines: osmium phosphido (PH2) complexes

Stable osmium phosphido complexes, Os(η2-chelate)(PH2)(CO)(PPh3)2, (chelate = acetate, N,N-dimethyldithiocarbamate, acetylacetonate, or nitrite) have been prepared by treating ClO4 with sodium acetate, sodium N,N-di

Synthesis and Structure of a P-Metallated Phospha-alkene, (CO)2(PPh3)2>

The terminal PH2-complex, , when treated with (CF3CO)2O gives CF3)>Cl(CO)2(PPh3)2> and this compound is dehydrochlorinated by NaH in tetrahydrofuran yielding the putative phosphinidene species, CF3)(CO)2(PPh3)2>