1039339-29-1Relevant articles and documents
Rh soaked in polyionic gel: An effective catalyst for dehydrogenative silylation of ketones
Thiot, Carine,Wagner, Alain,Mioskowski, Charles
, p. 5939 - 5942 (2006)
(Chemical Equation Presented) A polyionic gel-soaked Rh catalyst allows the formation of synthetically useful diphenylsilyl (DPS) enols under mild conditions. The reaction proceeds through dehydrogenative silylation of ketones, affording the kinetic silyl
Iron-Catalyzed Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions
Wekesa, Francis S.,Arias-Ugarte, Renzo,Kong, Lydia,Sumner, Zachary,McGovern, Gregory P.,Findlater, Michael
, p. 5051 - 5056 (2015/11/09)
Exposure of aldehyde or ketone to 1 mol % BIAN-Fe(C7H8) complex in the presence of diphenyl silane affords the corresponding protected alcohol in excellent yields, under mild reaction conditions. Aldehydes and ketones are reduced cleanly in the presence of a broad range of functional groups under solvent-free conditions.