1039704-09-0

Basic information

• Product Name: (2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid
• Synonyms: (2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid
• CAS NO: 1039704-09-0
• Molecular Weight: 234.37
• Mol File: 1039704-09-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid(1039704-09-0)
• EPA Substance Registry System: (2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid(1039704-09-0)

Safety Data

• Hazardous Substances Data: 1039704-09-0(Hazardous Substances Data)

Upstream product

• 109481-98-3 (Z)-3-Phenyl-2-trimethylsilanylmethyl-acrylic acid ethyl ester 

Relevant articles and documents

Correlation of hydrolysis and desilylation of 2-[(trimethylsilyl)methyl] acrylate derivatives in aqueous alkali solutions

Hydrolysis and desilylation reaction of 2-[(trimethylsilyl)methyl]acrylate (=2-[(trimethylsilyl)methyl] prop-2-enoate) derivatives were studied to evaluate the effect of the presence/absence of a further conjugating substituent (Schemes 3 and 4 and Tables 1 and 2). The substrates having a nonconjugating substituent at the acrylate moiety were stable to dilute alkali conditions, and afforded simple hydrolysis products under concentrated alkali conditions. In contrast, both hydrolysis and desilylation occurred from the substrates bearing conjugated substituents at the acrylate skeleton. The difference in reactivity can be explained in terms of the stabilization of the intermediate anion.