103979-34-6

Basic information

• Product Name: N-acetylphenylacetamidoxime
• Synonyms: N-acetylphenylacetamidoxime
• CAS NO: 103979-34-6
• Molecular Weight: 192.217
• Mol File: 103979-34-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-acetylphenylacetamidoxime(CAS DataBase Reference)
• NIST Chemistry Reference: N-acetylphenylacetamidoxime(103979-34-6)
• EPA Substance Registry System: N-acetylphenylacetamidoxime(103979-34-6)

Safety Data

• Hazardous Substances Data: 103979-34-6(Hazardous Substances Data)

Upstream product

• 701-72-4 phenylacetohydroximoyl chloride 
• 2620-30-6 sodium acetylamide 
• 7028-48-0 Phenylacetaldehyde oxime 

Downstream Products

• 538-32-9 benzylurea 

Relevant articles and documents

THE PHOTOELIMINATION OF N-NITROSO-N-ACETYL-α-AMINO-ACIDS; A NEW SYNTHESIS OF 1,2,4-OXADIAZOLES

The excitation of N-nitroso-N-acetyl-α-aminoacids, nitrosopeptide model compounds, under neutral and weakly basic conditions, caused the homolysis of the N-N bond followed by decarboxylation to give hyponitrous acid (HNO) and N-acetylimines which were susceptible to nucleophilic addition.While weak bases caused the carboxylate group to assist intramolecular rearrangement to a small extent, they functioned primarily to provide nucleophilic NO-, which initiated nucleophilic attack leading to the C-nitroso derivatives.These C-nitroso derivatives spontaneously cyclized to 1,2,4-oxadiazoles much more rapidly than tautomerism to the corresponding oximes; the latter oximes failed to cyclize under the basic conditions.