104023-33-8Relevant articles and documents
Enantioselective allylic thioetherification: The effect of phosphoric acid diester on iridium-catalyzed enantioconvergent transformations
Roggen, Markus,Carreira, Erick M.
supporting information; experimental part, p. 8652 - 8655 (2012/10/08)
You'll take the high road and I'll take the low road: Enantioenriched allylic thioethers have been synthesized from chiral racemic allylic alcohols. The combination of an Ir-(P,alkene) complex and dibutyl phosphoric acid are required to attain high select
Synthesis of naturally occurring cinnamyl cinnamates
Mali,Papalkar
, p. 433 - 435 (2007/10/03)
A convenient, high yield and general method is described for the synthesis of cinnamyl cinnamates (1a-f, 2a-c and 2e) from benzaldehydes (7a-f). The aldehydes (7a-f) on reaction with phosphorane (6) provide the (E,E)- cinnamyl cinnamates (1a-f) in high yields together with the (E,Z)- esters (2a-c and 2e) in low yields in the same reaction.