104066-53-7Relevant articles and documents
Gold-catalyzed cycloisomerizations of ene-ynamides
Couty, Sylvain,Meyer, Christophe,Cossy, Janine
experimental part, p. 1809 - 1832 (2009/06/28)
The gold-catalyzed cycloisomerizations of 1,6-ene-ynamides proceed under mild conditions and lead to cyclobutanones from terminal or trimethylsilyl substituted ynamides, or to carbonyl compounds bearing a 2,3-methanopyrrolidine subunit from substrates pos
COPPER CATALYZED SILYLZINCATION OF ACETYLENES
Okuda, Yasuhiro,Wakamatsu, Kuni,Tueckmantel, Werner,Oshima, Koichiro,Nozaki, Hitosi
, p. 4629 - 4632 (2007/10/02)
Dialkyl(dimethylphenylsilyl)zinclithium adds effectively to internal acetylenes as well terminal acetylenes in the presence of CuCN catalyst.