104092-38-8

Basic information

• Product Name: Cyclohexanol, 4-(2-methylpropyl)-
• Synonyms: 4-isobutylcyclohexanol;4-isobutylcyclohexan-1-ol
• CAS NO: 104092-38-8
• Molecular Formula: C10H20O
• Molecular Weight: 156.268
• Mol File: 104092-38-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 4-(2-methylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 4-(2-methylpropyl)-(104092-38-8)
• EPA Substance Registry System: Cyclohexanol, 4-(2-methylpropyl)-(104092-38-8)

Safety Data

• Hazardous Substances Data: 104092-38-8(Hazardous Substances Data)

Upstream product

• 4167-74-2 4-isobutylphenol 
• 29852-75-3 4-(2-Methyl-propenyl)-cyclohexanol 
• 42061-72-3 4-isobutylcyclohexanone 

Downstream Products

• 42061-72-3 4-isobutylcyclohexanone 

Relevant articles and documents

PERFUMES COMPRISING 4-ISOBUTYLCYCLOHEXANOLS

The invention concerns perfumes and perfumed products comprising 4-isobutylcyclohexanols according to formula (I), wherein R1 represents hydrogen or a methyl or ethyl group and R2 represents hydrogen or a methyl group. The invention also concerns compounds according to formula (I) wherein R1 represents a methyl or ethyl group and R2 represents hydrogen or a methyl group.

ENZYMATIC "IN VITRO" REDUCTION OF KETONES. VI.(1) Reduction rates and stereochemistry of the HLAD-catalyzed reduction of 3-alkyl- and 4-alkylcyclohexanones.

Reaction rate constants for the catalytic step HLAD-NADH + ketone * HLAD-NAD+ + alcohol in the HLAD-catalyzed reduction of 3-alkyl- and 4-alkylcyclohexanones are determined from initial rate measurements in the coenzyme recycling system ketone-ethanol-NAD+-HLAD.By rate measurements at several temperatures, activation parameters were determined and isokinetic relationships tracked down.Two different isokinetic relationships show that the 3-alkylcyclohexanones pass through an other type of transition state than cyclohexanone and the 4-alkylcyclohexanones, which means that they have a different arrangement on the HLAD-NADH complex.The results are rationalized in view of the most recent principles on nucleophilic additions to carbonyl functions.The resulting model for the HLAD-catalyzed reduction adequately explains the observed rate accelerating and decelerating effects and the stereochemistry of the reduction as well.