104144-02-7

Basic information

• Product Name: benzyl(1-cyano-4-pentenyl)amine
• CAS NO: 104144-02-7
• Molecular Weight: 200.283
• Mol File: 104144-02-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl(1-cyano-4-pentenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl(1-cyano-4-pentenyl)amine(104144-02-7)
• EPA Substance Registry System: benzyl(1-cyano-4-pentenyl)amine(104144-02-7)

Safety Data

• Hazardous Substances Data: 104144-02-7(Hazardous Substances Data)

Upstream product

• 2100-17-6 4-pentenal 
• 151-50-8 potassium cyanide 
• 3287-99-8 benzylamine hydrochloride 

Downstream Products

• 104144-03-8 N-(1-cyano-4-pentenyl)-N-<(phenylthio)methyl>benzenemethanamine 

Relevant articles and documents

Utilization of Phenylthio Substituted Amines for the Synthesis of Pyrrolidines

α-Phenylthio substituted amines have been found to be convenient reagents for the preparation of the pyrrolidine ring.Benzylamine (2) undergoes 1,3-dipolar cycloaddition with several dipolarophiles in the presence of silver fluoride.The reaction is believed to proceed via the intermediacy of an azomethine ylide.Treatment of α-(phenylthio)cyanoamines 10 and 17 with strong base results in the loss of the phenylthio group, and formation of substituted trans-piperazines 21, 22 in the case of 17.The mechanism of the reaction involves dimerization of the initially formed cyano substituted azomethine ylide intermediate, which behaves as a captodative diradical.Finally, the reaction of several alkenylamines with tributyltin hydride was studied as a method for generating the pyrrolidine ring via a radical cyclization reaction.