1042436-09-8

Basic information

• Product Name: N(P(C₆H₅)3)2⁽¹⁺⁾*Au(C₄S₃(C₆H₄OCH₃)2)2^(1-)=N(P(C₆H₅)3)2Au(C₄S₃(C₆H₄OCH₃)2)2
• CAS NO: 1042436-09-8
• Molecular Weight: 1452.57
• Mol File: 1042436-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N(P(C₆H₅)3)2⁽¹⁺⁾*Au(C₄S₃(C₆H₄OCH₃)2)2^(1-)=N(P(C₆H₅)3)2Au(C₄S₃(C₆H₄OCH₃)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: N(P(C₆H₅)3)2⁽¹⁺⁾*Au(C₄S₃(C₆H₄OCH₃)2)2^(1-)=N(P(C₆H₅)3)2Au(C₄S₃(C₆H₄OCH₃)2)2(1042436-09-8)
• EPA Substance Registry System: N(P(C₆H₅)3)2⁽¹⁺⁾*Au(C₄S₃(C₆H₄OCH₃)2)2^(1-)=N(P(C₆H₅)3)2Au(C₄S₃(C₆H₄OCH₃)2)2(1042436-09-8)

Safety Data

• Hazardous Substances Data: 1042436-09-8(Hazardous Substances Data)

Upstream product

• 121772-60-9 bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) 
• 1042436-03-2 4,6-bis(4-methoxyphenyl)-thieno[3,4-d]-1,3-dithiol-2-one 

Relevant articles and documents

Novel dithiolene complexes incorporating conjugated electroactive ligands

A series of new metal (M) dithiolene complexes bearing terthiophene (3, 12, M = Ni; 4, M = Pd; 5, 6, M = Au) and 2,5-bis(para-methoxyphenyl)thiophene units (14, M = Ni; 15, 16, M = Au; 17, M = Pd) have been synthesised in 38-99% yield. The electrochemical properties of the materials have been characterised by cyclic voltammetry and UV-vis spectroelectrochemistry. The nickel complexes possess low oxidation potentials (-0.12 to -0.25 V vs Ag/AgCl) due to the electron-rich dithiolene centres and all complexes display ligand-based redox activity. The terthiophene derivatives have been polymerised by electrochemical oxidation to give stable films with, in the case of poly(3), broad absorption characteristics. Charge transfer materials have been isolated from 14 and 16 with conductivities in the range 9 × 10-6 to 7 × 10 -8 S cm-1. The Royal Society of Chemistry 2008.