104266-25-3

Basic information

• Product Name: (R)-2-acetoxy-2,6,6-trimethylcyclohexanone
• Synonyms: (R)-2-acetoxy-2,6,6-trimethylcyclohexanone
• CAS NO: 104266-25-3
• Molecular Weight: 198.262
• Mol File: 104266-25-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-2-acetoxy-2,6,6-trimethylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-acetoxy-2,6,6-trimethylcyclohexanone(104266-25-3)
• EPA Substance Registry System: (R)-2-acetoxy-2,6,6-trimethylcyclohexanone(104266-25-3)

Safety Data

• Hazardous Substances Data: 104266-25-3(Hazardous Substances Data)

Upstream product

• 546-67-8 lead(IV) tetraacetate 
• 88794-46-1 (-)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-methanol 
• 104266-23-1 (R)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexanone 
• 108-24-7 acetic anhydride 
• 104266-24-2 (R)-2-hydroxy-2,6,6-trimethylcylohexanone 

Downstream Products

• 17092-92-1 (7aR)-5,6,7,7a-tetrahydro-4,4,7a-trimethyl-2(4H)-benzofuranone 

Relevant articles and documents

Lead(IV) acetate oxidative ring-opening of 2,3-epoxy primary alcohols: A new entry to optically active α-hydroxy carbonyl compounds

The treatment of 2,3-epoxy primary alcohols with lead(IV) acetate (LTA) leads to α-acetoxy aldehydes or α-acetoxy ketones, through the nucleophilic ring-opening of an intermediate oxonium and the subsequent carbon-carbon bond cleavage. This reaction repre

ASYMMETRIC SYNTHESIS OF (5R,6R)-AEGINETOLIDE AND (5R)-DIHYDROACTINIDIOLIDE FROM (R)-2-HYDROXY-2-METHYLCYCLOHEXANONE

C11-Cyclic terpenes, (5R,6R)-(-)-aeginetolide and (5R)-(-)-dihydroactinidiolide have been synthesized stereoselectively starting from (R)-2-hydroxy-2-methylcyclohexanone in short steps.