104321-86-0

Basic information

• Product Name: (R)-3-Methyl-pentanoic acid (1R,2R,3S,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester
• CAS NO: 104321-86-0
• Molecular Weight: 511.726
• Mol File: 104321-86-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-3-Methyl-pentanoic acid (1R,2R,3S,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-Methyl-pentanoic acid (1R,2R,3S,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester(104321-86-0)
• EPA Substance Registry System: (R)-3-Methyl-pentanoic acid (1R,2R,3S,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester(104321-86-0)

Safety Data

• Hazardous Substances Data: 104321-86-0(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 104321-80-4 (E)-Pent-2-enoic acid (1R,2R,3S,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 

Downstream Products

• 16958-25-1 (R)-3-methylpentanoic acid 

Relevant articles and documents

ASYMMETRIC SYNTHESIS OF β-SUBSTITUTED ALCANOIC ACIDS VIA HIGHLY STEREOSELECTIVE CONJUGATE ADDITIONS OF ORGANOCOPPER COMPOUNDS TO CHIRAL ENOATES

Conjugate additions of organocopper compounds RCu*BF3 to enoates of sulfonamide-shielded alcohols 1x and 1n quite generally proceed with >99percent ee and >90percent yield.