104429-45-0Relevant articles and documents
Palladium-catalyzed alkoxycarbonylation of (Z)-2-en-4-yn carbonates leading to 2,3,5-trienoates
Akpinar, G. Eray,Kus, Melih,Uecuencue, Muhammed,Karakus, Erman,Artok, Levent
, p. 748 - 751 (2011/04/24)
Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an exclusively E-configuration and in high yields. The fact that no such reactivity could be observed with
STEREOSELECTIVE SYNTHESIS AND THERMAL BEHAVIOR OF (Z)-EPOXYHEXENYNES: A SIMPLE AND GENERAL ROUTE TO 2-VINYLFURANS
Eberbach, Wolfgang,Roser, Joachim
, p. 2797 - 2802 (2007/10/02)
An efficient approach for the synthesis of 2,3-disubstituted furans (2a-j/3a-j) is described by using the thermally induced rearrangement of epoxyhexenynes (1a-j) which are prepared by streoselective synthesis of the (Z)-pentenynals 10 and subsequent Darz