104554-43-0Relevant articles and documents
Synthesis and combined properties of novel fluorinated cationic surfactants derived from hexafluoropropylene dimer
Lin, Chao,Pan, Renming,Xing, Ping,Jiang, Biao
, p. 1613 - 1616 (2018)
Three novel fluorinated cationic surfactants were prepared by adopting perfluoro-2-methyl-2-pentene as raw substrate. The as-obtained fluorinated cationic surfactants exhibited excellent surface properties, all of them can reduce the surface tension of wa
Synthesis and surface activity study of branched fluorinated cationic (FCS), gemini (FGS) and amphoteric (FAS) surfactants with CF3CF2CF2C(CF3)2 group
Sha, Min,Pan, Renming,Xing, Ping,Jiang, Biao
, p. 61 - 65 (2015)
Fluorinated surfactants are usually composed of a perfluorinated chain and a hydrophilic group. Academic surveys have reported that straight chain fluorinated surfactants have the lowest surface tension in a relatively high concentration while the branched fluorinated surfactants show more efficient in a relatively low concentration. Introducing branch is one of effective strategies for synthesis of non-bioaccumulable fluorinated surfactants. Three novel branched fluorinated surfactants were designed and prepared through a five-step route using perfluoro-2-methyl-2-pentene as starting material. The surface activities of them were investigated and found that they exhibited excellent surface activities. FCS can reduce the surface tension of water to below 20 mN/m, and the cmc value of FAS in water is about 1.04 × 10-4 mol/L at 298 K. All the values of surface properties of FCS, FGS and FAS are lower than that of sodium perfluorooctanoate.
Reactions involving fluoride ion. Part 44.1 Synthesis, and chemistry of aromatics with bulky perfluoroalkyl substituents
Chambers, Richard D.,Magron, Corinne,Sandford, Graham
, p. 283 - 290 (2007/10/03)
The observable perfluoroalkyl carbanion la, generated by addition of fluoride ion to perfluoroalkene 1, reacts efficiently with benzyl bromide, and a range of related derivatives 3a-g, and this provides methodology for the preparation of aromatic rings wi