104557-13-3

Basic information

• Product Name: N⁶,N⁶,2',3',5'-penta-O-toluoyladenosine
• Synonyms: N⁶,N⁶,2',3',5'-penta-O-toluoyladenosine
• CAS NO: 104557-13-3
• Molecular Weight: 857.92
• Mol File: 104557-13-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N⁶,N⁶,2',3',5'-penta-O-toluoyladenosine(CAS DataBase Reference)
• NIST Chemistry Reference: N⁶,N⁶,2',3',5'-penta-O-toluoyladenosine(104557-13-3)
• EPA Substance Registry System: N⁶,N⁶,2',3',5'-penta-O-toluoyladenosine(104557-13-3)

Safety Data

• Hazardous Substances Data: 104557-13-3(Hazardous Substances Data)

Upstream product

• 933-88-0 ortho-toluoyl chloride 
• 58-61-7 adenosine 

Downstream Products

• 104557-11-1 N⁶,3',5'-tri-O-toluoyladenosine 
• 104557-12-2 C₃₄H₃₁N₅O₇ 

Relevant articles and documents

REGIOSELECTIVE PROTECTION OF CARBOHYDRATE DERIVATIVES. PART. 20. SIMPLE, EFFICIENT 2'-O-DEACYLATION OF FULLY ACYLATED PURINE AND PYRIMIDINE RIBONUCLEOSIDES THROUGH tert-BUTOXIDE

A simple treatment of fully aroylated purine and pyrimidine ribonucleosides with pulverized potassium tert-butoxide in tetrahydrofuran (THF) or dichloromethane under a controlled condition gave a mixture of the corresponding di-O-aroyl derivatives in which 2'-OH derivatives are preponderant over 3'-OH derivatives; 3',5'-di-O-benzoyluridine, N4,3',5'-tribenzoylcytidine, N4,3',5'-tri-O-toluoylcytidine, N2,3',5'-tribenzoylguanosine, and N2,isobutyryl-3',5'-di-O-benzoylguanosine were obtained crystalline in 80 percent, 78 percent, 72 percent, 67 percent, and 65 percent yields, respectively.