104669-20-7

Basic information

• Product Name: 11-benzyloxy-10-methoxy-7,8-dihydro-5H-benzopyrido<3,4-g>quinolizin-5-one
• Synonyms: 11-benzyloxy-10-methoxy-7,8-dihydro-5H-benzopyrido<3,4-g>quinolizin-5-one
• CAS NO: 104669-20-7
• Molecular Weight: 384.434
• Mol File: 104669-20-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 11-benzyloxy-10-methoxy-7,8-dihydro-5H-benzopyrido<3,4-g>quinolizin-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: 11-benzyloxy-10-methoxy-7,8-dihydro-5H-benzopyrido<3,4-g>quinolizin-5-one(104669-20-7)
• EPA Substance Registry System: 11-benzyloxy-10-methoxy-7,8-dihydro-5H-benzopyrido<3,4-g>quinolizin-5-one(104669-20-7)

Upstream product

• 120155-05-7 7-benzyloxy-6-methoxy-1-methylene-2-nicotinyl-1,2,3,4-tetrahydroisoquinoline 
• 104669-18-3 Acetic acid (12S,12aR)-2-benzyloxy-3-methoxy-7-oxo-5,7,12,12a-tetrahydro-6H-6a,9-diaza-benzo[a]anthracen-12-yl ester 
• 54-86-4 sodium nicotinate 
• 78867-50-2 7-(benzyloxy)-6-methoxy-1-methyl-3,4-dihydroisoquinoline 
• 10400-19-8 3-pyridinecarbonyl chloride 
• 104669-15-0 (12S,12aR)-2-Benzyloxy-12-hydroxy-3-methoxy-5,6,12,12a-tetrahydro-6a,9-diaza-benzo[a]anthracen-7-one 
• 55803-41-3 N-formyl-2-[3-methoxy-4-(benzyloxy)phenyl]ethylamine 
• 15357-92-3 6-methoxy-7-(benzyloxy)-3,4-dihydroisoquinoline 
• 4664-08-8 cinchomeronic anhydride 
• 5657-52-3 1,3-dihydrofuro<3,4-c>pyridin-3-one 

Downstream Products

• 115757-54-5 (6aR,12aS)-2-Benzyloxy-3-methoxy-5,7,12,12a-tetrahydro-6H-6a,9-diaza-benzo[a]anthracene 
• 115757-50-1 11-benzyloxy-10-methoxy-7,8-dihydro-5H-benzopyrido<3,4-g>quinolizin-5-thione 
• 107588-80-7 (8R*,13aS*)-2-benzyloxy-5,6,13,13a-tetrahydro-3-methoxy-8-methyl-8H-isoquino<2,1-b><2,7>naphthyridine 
• 107588-80-7 (8S*,13aS*)-2-benzyloxy-5,6,13,13a-tetrahydro-3-methoxy-8-methyl-8H-isoquino<2,1-b><2,7>naphthyridine 

Relevant articles and documents

STUDIES ON INDIAN MEDICINAL PLANTS : PART 91 - STRUCTURE AND SYNTHESIS OF ALAMARIDINE. A NOVEL 5-METHYLBENZOPYRIDOQUINOLIZINE ALKALOID FROM ALANGIUM LAMARCKII

The structure of alamaridine (1), a novel benzopyridoquinolizine alkaloid, was established by spectral data.However, its stereochemistry could only be determined now by a total synthesis involving the key cyclisation of an 1-methyl-2-pyridylmethyl-3,4-dihydroisoquinolinium salt 19a in presence of pivaloyl chloride and triethylamine.O-Benzyldehydroalamaridine thus formed was reduced by sodium cyanoborohydride and then deprotected to obtain alamaridine (1) and 5-epi-alamaridine (26).Isoalamaridine (27) and its 5-epimer (28) were also synthesised following the same route.