104706-75-4

Basic information

• Product Name: (E)-5-(Benzhydrylidene-amino)-hex-2-enedioic acid dimethyl ester
• CAS NO: 104706-75-4
• Molecular Weight: 351.402
• Mol File: 104706-75-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-5-(Benzhydrylidene-amino)-hex-2-enedioic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-5-(Benzhydrylidene-amino)-hex-2-enedioic acid dimethyl ester(104706-75-4)
• EPA Substance Registry System: (E)-5-(Benzhydrylidene-amino)-hex-2-enedioic acid dimethyl ester(104706-75-4)

Safety Data

• Hazardous Substances Data: 104706-75-4(Hazardous Substances Data)

Upstream product

• 1117-71-1 methyl-4-bromo-2-butenoate 
• 81167-39-7 methyl N-(diphenylmethylene)glycinate 

Relevant articles and documents

REACTION OF SCHIFF BASES ANIONS WITH 4-HALO-2-BUTENOATES : SELECTIVE SYNTHESIS OF α-CYCLOPROPYL AND γ,δ UNSATURATED α-AMINO ACID DERIVATIVES.

Depending on the reaction conditions, anions of imines derived from α-aminoesters react with 4-bromo-2-butenoates to give either cyclopropyl derivatives by an addition-elimination or γ,δ-unsaturated iminoesters by a nucleophilic substitution.