104729-88-6Relevant articles and documents
Elucidation of the stereochemistry of thiirane formation from a 1λ4,2-dithietane bearing two chiral carbon centers
Kusaka, Shinpei,Kano, Naokazu,Kawashima, Takayuki
, p. 412 - 417 (2010)
A tetracoordinated sulfurane bearing a 1λ4,2-dithietane moiety, whose 3- and 4-positions were chiral carbon centers, was synthesized. Its thermolysis gave the corresponding thiirane as a single diastereomer, whose configuration and stereochemis
Straightforward iron-catalyzed synthesis of vinylboronates by the hydroboration of alkynes
Haberberger, Michael,Enthaler, Stephan
supporting information, p. 50 - 54 (2013/02/23)
An iron-catalyzed hydroboration of alkynes to produce vinylboronates has been examined. With a straightforward system composed of iron carbonyls and pinacolborane, good to excellent yields and chemoselectivities were achieved for a variety of alkynes. Cop