104755-32-0

Basic information

• Product Name: Ethanone, 1-(4-nitrophenyl)-2-(phenylseleno)-
• CAS NO: 104755-32-0
• Molecular Formula: C14H11NO3Se
• Molecular Weight: 320.206
• Mol File: 104755-32-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(4-nitrophenyl)-2-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4-nitrophenyl)-2-(phenylseleno)-(104755-32-0)
• EPA Substance Registry System: Ethanone, 1-(4-nitrophenyl)-2-(phenylseleno)-(104755-32-0)

Safety Data

• Hazardous Substances Data: 104755-32-0(Hazardous Substances Data)

Upstream product

• 100-19-6 (4-nitrophenyl)ethanone 
• 100-13-0 4-nitrostyrene 
• 1666-13-3 diphenyl diselenide 
• 645-96-5 Benzeneselenol 
• 42572-42-9 phenylselenium trichloride 
• 99-81-0 4-Nitrophenacyl bromide 
• 41924-21-4 phenyl tributylstannyl selenide 
• 104755-15-9 C₁₄H₁₁Cl₂NO₃Se 

Downstream Products

• 14971-39-2 benzeneselenolate ion 
• 1666-13-3 diphenyl diselenide 
• 100-19-6 (4-nitrophenyl)ethanone 

Relevant articles and documents

Visible-light-induced oxidative coupling of vinylarenes with diselenides leading to α-aryl and α-alkyl selenomethyl ketones

A visible-light-induced oxidative coupling of diselenides with readily available vinylarenes is demonstrated. This benign protocol allows one to access a wide range of α-aryl and α-alkyl selenomethyl ketones in good yields with excellent functional group compatibility. The distinct advantages of this protocol over all previous methods include the use of a green solvent and air as an oxidant and the lack of a photocatalyst, a base, and an oxidant as well as better green chemistry matrices. Furthermore, the title reaction can be performed with natural sunlight, the most sustainable energy source imaginable. Additionally, the mild reaction conditions, easy operation and suitability for the modification of styrene-functionalized biomolecules make the current reaction system a more attractive method for the synthesis of a variety of medicinal and agrochemical compounds of interest.

PHENYL SELENIUM TRICHLORIDE IN SYNTHESIS. REACTION WITH KETONES. A NEW VARIATION OF THE SELENOXIDE ELIMINATION REACTION

Phenyl selenium trichloride was used for the introduction of a PhSeCl2-group into the α-position of ketones.These products were converted to enones (hydrolysis/selenoxide elimination) or α-phenylselenoketones (thiourea-reduction).